Print Page | Contact Us | Report Abuse | Sign In | Register
Graphene Updates
Blog Home All Blogs
The latest news and information on all aspects of graphene research, development, application and commercialization.

 

Search all posts for:   

 

Top tags: Graphene  2D materials  Batteries  Sensors  Li-ion batteries  University of Manchester  CVD  Electronics  First Graphene  graphene production  nanomaterials  graphene oxide  The Graphene Flagship  coatings  graphite  Applied Graphene Materials  Energy Storage  Haydale  Carbon Nanotubes  composites  Andre Geim  Battery  biosensors  Gratomic  Hexagonal boron nitride  optoelectronics  Standards  Versarien  3D Printing  Adrian Potts 

UVA researchers devise method for converting retired Li-ion anodes to graphene and GO

Posted By Terrance Barkan, Saturday, December 29, 2018

Researchers at the University of Virginia (UVA) have devised a process for converting retired Li-ion battery anodes to graphene and graphene oxide (GO). A paper on the work is published in the ACS journal Nano Letters.

Schematic illustration of the proposed smart fabrication of graphene and graphene oxide from end-of-life batteries. Zhang et al.

… accompanying the booming expansion of the Li-ion battery market, a tremendous amount of batteries retire every year and most of them are disposed of in landfills, which not only causes severe waste of precious sources but also induces hazardous soil contamination due to the plastic components and toxic electrolytes. So far, only 1% of end-of-life Li-ion batteries have been recycled. Apparently, it is an urgent necessity to develop effective battery recycling techniques. 

… A rational strategy to simultaneously solve the environmental issues from waste batteries and graphite mining is to fabricate graphene directly from end-of-life battery anodes.

 

… Here, graphite powders from end-of-life Li-ion battery anodes were used to fabricate graphene.

—Zhang et al.

Graphite powders collected from end-of-life Li-ion batteries exhibited irregular expansion because of the lithium-ion intercalation and deintercalation in the anode graphite during battery charge/discharge. 

Such lattice expansion of graphite can be considered as a prefabrication of graphene because it weakened the van der Waals bonds and facilitated the exfoliation. 

—Zhang et al.

 

This “prefabrication” process facilitates both chemical and physical exfoliations of the graphite. Comparing with the graphene oxide derived from pristine, untreated graphite, the graphene oxide from anode graphite exhibited excellent homogeneity and electrochemical properties. 

The lithiation aided pre-expansion enabled 4 times enhancement of graphene productivity by shear mixing, the researchers found. 

The graphene fabrication was seamlessly inserted into the currently used battery recycling streamline in which acid treatment was found to further swell the graphite lattice, pushing up the graphene productivity to 83.7% (10 times higher than that of pristine graphite powders).

Tags:  Batteries  Graphene  graphene oxide  Li-ion  Li-ion batteries  UVA 

Share |
PermalinkComments (0)